Chiral cyclopentadienyl Rh(III)-catalyzed enantioselective cyclopropanation of electron-deficient olefins enable rapid access to UPF-648 and oxylipin natural products

Chiral cyclopentadienyl Rh(III) complexes efficiently catalyze enantioselective cyclopropanations of electron-deficient olefins with N-enoxysuccinimides as the C1 unit. Excellent asymmetric inductions and high diastereoselectivities can be obtained for a wide range of substrate combinations. The rea...

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Detalles Bibliográficos
Autores principales: Duchemin, Coralie, Cramer, Nicolai
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419935/
https://www.ncbi.nlm.nih.gov/pubmed/30996996
http://dx.doi.org/10.1039/c8sc05702h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419935/
https://www.ncbi.nlm.nih.gov/pubmed/30996996
http://dx.doi.org/10.1039/c8sc05702h

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