Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports

Single-site Ir(CO)(2) complexes bonded to high-surface-area metal oxide supports, SiO(2), TiO(2), Fe(2)O(3), CeO(2), MgO, and La(2)O(3), were synthesized by chemisorption of Ir(CO)(2)(acac) (acac = acetylacetonate) followed by coating with each of the following ionic liquids (ILs): 1-n-butyl-3-methy...

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Detalles Bibliográficos
Autores principales: Babucci, Melike, Fang, Chia-Yu, Perez-Aguilar, Jorge E., Hoffman, Adam S., Boubnov, Alexey, Guan, Erjia, Bare, Simon R., Gates, Bruce C., Uzun, Alper
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419936/
https://www.ncbi.nlm.nih.gov/pubmed/30996978
http://dx.doi.org/10.1039/c8sc05287e

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419936/
https://www.ncbi.nlm.nih.gov/pubmed/30996978
http://dx.doi.org/10.1039/c8sc05287e

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