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Perfluoroalkylative pyridylation of alkenes via 4-cyanopyridine-boryl radicals
A metal-free and photo-free method for the perfluoroalkylative pyridylation of alkenes has been developed via a combination of computational and experimental studies. Density functional theory calculations and control experiments indicate that the homolysis of R(f)–X (X = Br, I) bonds by the 4-cyano...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6419949/ https://www.ncbi.nlm.nih.gov/pubmed/30996995 http://dx.doi.org/10.1039/c8sc05237a |