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Norcorrole as a Delocalized, Antiaromatic System

Nickel norcorrole provides an unusual example of a molecule that is strongly antiaromatic according to the magnetic criterion, but which exhibits, according to high-quality DFT calculations, a symmetric, delocalized structure with no difference in bond length between adjacent C(meso)-C(α) bonds. A f...

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Detalles Bibliográficos
Autores principales: Conradie, Jeanet, Foroutan-Nejad, Cina, Ghosh, Abhik
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6425022/
https://www.ncbi.nlm.nih.gov/pubmed/30890733
http://dx.doi.org/10.1038/s41598-019-39972-y