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Heterolytic bond activation at gold: evidence for gold(iii) H–B, H–Si complexes, H–H and H–C cleavage
The coordinatively unsaturated gold(iii) chelate complex [(C^N–CH)Au(C(6)F(5))](+) (1(+)) reacts with main group hydrides H–BPin and H–SiEt(3) in dichloromethane solution at –70 °C to form the corresponding σ-complexes, which were spectroscopically characterized (C^N–CH = 2-(C(6)H(3)Bu(t))-6-(C(6)H(...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6425858/ https://www.ncbi.nlm.nih.gov/pubmed/30996979 http://dx.doi.org/10.1039/c8sc05229h |