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Making the unconventional μ(2)-P bridging binding mode more conventional in phosphinine complexes
Phosphinines, as aromatic heterocycles, usually engage in coordination as η(1)-P σ-complexes or η(6)-phosphinine π-complexes. The μ(2)-P bridging coordination mode is rarely observed. With the aim to study the effect of different electronic configurations of phosphinines on the coordination modes, a...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6427944/ https://www.ncbi.nlm.nih.gov/pubmed/30996898 http://dx.doi.org/10.1039/c8sc05281f |