Cargando…

Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity

The parameters for metal-organic chemical vapor deposition (MOCVD) processes significantly influence the properties of ZnO films, especially the flow stability of the chamber, which is caused by process parameters such as the shape of reaction chamber, the working pressure, the growth temperature, t...

Descripción completa

Detalles Bibliográficos
Autores principales: Li, Jian, Wu, Ziling, Xu, Yifeng, Pei, Yanli, Wang, Gang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429165/
https://www.ncbi.nlm.nih.gov/pubmed/30832241
http://dx.doi.org/10.3390/molecules24050876
_version_ 1783405534488035328
author Li, Jian
Wu, Ziling
Xu, Yifeng
Pei, Yanli
Wang, Gang
author_facet Li, Jian
Wu, Ziling
Xu, Yifeng
Pei, Yanli
Wang, Gang
author_sort Li, Jian
collection PubMed
description The parameters for metal-organic chemical vapor deposition (MOCVD) processes significantly influence the properties of ZnO films, especially the flow stability of the chamber, which is caused by process parameters such as the shape of reaction chamber, the working pressure, the growth temperature, the susceptor rotational speed, the gas flow rate, and the nature of the carrier gas at inlet temperature. These parameters are the preconditions for the formation of high-quality film. Therefore, this study uses Ar as a carrier gas, diethylzinc (DEZn) as a Zn source, and H(2)O as an oxygen source and adopts the reaction mechanism calculated by quantum chemistry, which includes ten gas reactions and eight surface reactions. The process parameters of a specific reaction chamber model were analyzed based on the computational fluid dynamics method. This study also presents an accurate prediction of the flow regime in the reactor chamber under any operating conditions, without additional experiments, based on an analysis of a great quantity of simulation data. Such research is also significant for selecting the growth parameters relevant to production, providing a specific process growth window, narrowing the debugging scope, and providing a theoretical basis for the development of MOCVD equipment and process debugging.
format Online
Article
Text
id pubmed-6429165
institution National Center for Biotechnology Information
language English
publishDate 2019
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-64291652019-04-15 Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity Li, Jian Wu, Ziling Xu, Yifeng Pei, Yanli Wang, Gang Molecules Article The parameters for metal-organic chemical vapor deposition (MOCVD) processes significantly influence the properties of ZnO films, especially the flow stability of the chamber, which is caused by process parameters such as the shape of reaction chamber, the working pressure, the growth temperature, the susceptor rotational speed, the gas flow rate, and the nature of the carrier gas at inlet temperature. These parameters are the preconditions for the formation of high-quality film. Therefore, this study uses Ar as a carrier gas, diethylzinc (DEZn) as a Zn source, and H(2)O as an oxygen source and adopts the reaction mechanism calculated by quantum chemistry, which includes ten gas reactions and eight surface reactions. The process parameters of a specific reaction chamber model were analyzed based on the computational fluid dynamics method. This study also presents an accurate prediction of the flow regime in the reactor chamber under any operating conditions, without additional experiments, based on an analysis of a great quantity of simulation data. Such research is also significant for selecting the growth parameters relevant to production, providing a specific process growth window, narrowing the debugging scope, and providing a theoretical basis for the development of MOCVD equipment and process debugging. MDPI 2019-03-01 /pmc/articles/PMC6429165/ /pubmed/30832241 http://dx.doi.org/10.3390/molecules24050876 Text en © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Li, Jian
Wu, Ziling
Xu, Yifeng
Pei, Yanli
Wang, Gang
Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity
title Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity
title_full Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity
title_fullStr Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity
title_full_unstemmed Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity
title_short Stability Analysis of Multi Process Parameters for Metal-Organic Chemical Vapor Deposition Reaction Cavity
title_sort stability analysis of multi process parameters for metal-organic chemical vapor deposition reaction cavity
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429165/
https://www.ncbi.nlm.nih.gov/pubmed/30832241
http://dx.doi.org/10.3390/molecules24050876
work_keys_str_mv AT lijian stabilityanalysisofmultiprocessparametersformetalorganicchemicalvapordepositionreactioncavity
AT wuziling stabilityanalysisofmultiprocessparametersformetalorganicchemicalvapordepositionreactioncavity
AT xuyifeng stabilityanalysisofmultiprocessparametersformetalorganicchemicalvapordepositionreactioncavity
AT peiyanli stabilityanalysisofmultiprocessparametersformetalorganicchemicalvapordepositionreactioncavity
AT wanggang stabilityanalysisofmultiprocessparametersformetalorganicchemicalvapordepositionreactioncavity