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Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment
We present three heterobimetallic complexes containing an isostructural nickel center and a lutetium ion in varying coordination environments. The bidentate (i)Pr(2)PCH(2)NHPh and nonadentate ((i)Pr(2)PCH(2)NHAr)(3)tacn ligands were used to prepare the Lu metalloligands, Lu((i)Pr(2)PCH(2)NPh)(3) (1)...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429466/ https://www.ncbi.nlm.nih.gov/pubmed/30996926 http://dx.doi.org/10.1039/c8sc04712j |