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Bimetallic nickel-lutetium complexes: tuning the properties and catalytic hydrogenation activity of the Ni site by varying the Lu coordination environment

We present three heterobimetallic complexes containing an isostructural nickel center and a lutetium ion in varying coordination environments. The bidentate (i)Pr(2)PCH(2)NHPh and nonadentate ((i)Pr(2)PCH(2)NHAr)(3)tacn ligands were used to prepare the Lu metalloligands, Lu((i)Pr(2)PCH(2)NPh)(3) (1)...

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Detalles Bibliográficos
Autores principales:	Ramirez, Bianca L., Sharma, Prachi, Eisenhart, Reed J., Gagliardi, Laura, Lu, Connie C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429466/ https://www.ncbi.nlm.nih.gov/pubmed/30996926 http://dx.doi.org/10.1039/c8sc04712j

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