Enantioselective intramolecular C–H amination of aliphatic azides by dual ruthenium and phosphine catalysis

The catalytic enantioselective intramolecular C(sp(3))-H amination of aliphatic azides represents an efficient method for constructing chiral saturated cyclic amines which constitute a prominent structural motif in bioactive compounds. We report a dual catalytic system involving a chiral-at-metal bi...

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Detalles Bibliográficos
Autores principales: Qin, Jie, Zhou, Zijun, Cui, Tianjiao, Hemming, Marcel, Meggers, Eric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429596/
https://www.ncbi.nlm.nih.gov/pubmed/30996902
http://dx.doi.org/10.1039/c9sc00054b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429596/
https://www.ncbi.nlm.nih.gov/pubmed/30996902
http://dx.doi.org/10.1039/c9sc00054b

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