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Enantioselective intramolecular C–H amination of aliphatic azides by dual ruthenium and phosphine catalysis
The catalytic enantioselective intramolecular C(sp(3))-H amination of aliphatic azides represents an efficient method for constructing chiral saturated cyclic amines which constitute a prominent structural motif in bioactive compounds. We report a dual catalytic system involving a chiral-at-metal bi...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429596/ https://www.ncbi.nlm.nih.gov/pubmed/30996902 http://dx.doi.org/10.1039/c9sc00054b |