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Monomeric Cp(3t)Al(i): synthesis, reactivity, and the concept of valence isomerism
With the isolation of Cp(3t)Al (1), the first monomeric Cp-based Al(i) species could be realized in a pure form via a three-step reaction sequence (salt elimination/adduct formation/adduct cleavage) starting from readily available AlBr(3). Due to its monomeric structure, reactions involving 1 were f...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429597/ https://www.ncbi.nlm.nih.gov/pubmed/30996931 http://dx.doi.org/10.1039/c8sc05175e |