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Monomeric Cp(3t)Al(i): synthesis, reactivity, and the concept of valence isomerism

With the isolation of Cp(3t)Al (1), the first monomeric Cp-based Al(i) species could be realized in a pure form via a three-step reaction sequence (salt elimination/adduct formation/adduct cleavage) starting from readily available AlBr(3). Due to its monomeric structure, reactions involving 1 were f...

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Detalles Bibliográficos
Autores principales: Hofmann, Alexander, Tröster, Tobias, Kupfer, Thomas, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429597/
https://www.ncbi.nlm.nih.gov/pubmed/30996931
http://dx.doi.org/10.1039/c8sc05175e

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