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Charge transfer dependence on CO(2) hydrogenation activity to methanol in Cu nanoparticles covered with metal–organic framework systems

We report the synthesis and characterization of highly active Cu nanoparticles covered with zirconium/hafnium-based metal–organic frameworks for CO(2) hydrogenation to methanol. Compared to Cu/γ-Al(2)O(3), Cu/ZIF-8, Cu/MIL-100 and Cu/UiO-66 composites, UiO-66 acts as the most active support, with Cu...

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Detalles Bibliográficos
Autores principales: Kobayashi, Hirokazu, Taylor, Jared M., Mitsuka, Yuko, Ogiwara, Naoki, Yamamoto, Tomokazu, Toriyama, Takaaki, Matsumura, Syo, Kitagawa, Hiroshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429599/
https://www.ncbi.nlm.nih.gov/pubmed/30996914
http://dx.doi.org/10.1039/c8sc05441j