Electrochemical fluoromethylation triggered lactonizations of alkenes under semi-aqueous conditions

An electrochemical difluoromethylation triggered lactonization of alkenes was developed for the first time. This protocol employs readily prepared CF(2)HSO(2)Na as the difluoromethylating reagent, affording unprecedented CF(2)H-containing lactones in moderate yields. Moreover, with CF(3)SO(2)Na as t...

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Detalles Bibliográficos
Autores principales: Zhang, Sheng, Li, Lijun, Zhang, Jinjin, Zhang, Junqi, Xue, Mengyu, Xu, Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429606/
https://www.ncbi.nlm.nih.gov/pubmed/30996899
http://dx.doi.org/10.1039/c9sc00100j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429606/
https://www.ncbi.nlm.nih.gov/pubmed/30996899
http://dx.doi.org/10.1039/c9sc00100j

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