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A new route for the efficient metalation of unfunctionalized aromatics
The synthesis and isolation of a novel bimetallic species formed by reacting two equivalents of TMPLi with CuCl in the presence of Et(2)O are reported. X-ray crystallography reveals the Et(2)O-free tetranuclear aggregate (TMPCu)(2)(TMPLi)(2)1, which formally results from the catenation of dimers of...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429619/ https://www.ncbi.nlm.nih.gov/pubmed/30996927 http://dx.doi.org/10.1039/c8sc04325f |