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A new route for the efficient metalation of unfunctionalized aromatics

The synthesis and isolation of a novel bimetallic species formed by reacting two equivalents of TMPLi with CuCl in the presence of Et(2)O are reported. X-ray crystallography reveals the Et(2)O-free tetranuclear aggregate (TMPCu)(2)(TMPLi)(2)1, which formally results from the catenation of dimers of...

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Detalles Bibliográficos
Autores principales:	Peel, Andrew J., Tezuka, Noriyuki, D'Rozario, James M., Uchiyama, Masanobu, Wheatley, Andrew E. H.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429619/ https://www.ncbi.nlm.nih.gov/pubmed/30996927 http://dx.doi.org/10.1039/c8sc04325f

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