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Addressing the properties of “Metallo-DNA” with a Ag(i)-mediated supramolecular duplex

The silver-nucleoside complex [Ag(i)-(N3-cytidine)(2)], 1, self-assembles to form a supramolecular metal-mediated base-pair array highly analogous to those seen in metallo-DNA. A combination of complementary hydrogen-bonding, hydrophobic and argentophilic interactions drive the formation of a double...

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Detalles Bibliográficos
Autores principales: Mistry, Liam, El-Zubir, Osama, Dura, Gema, Clegg, William, Waddell, Paul G., Pope, Thomas, Hofer, Werner A., Wright, Nick G., Horrocks, Benjamin R., Houlton, Andrew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429620/
https://www.ncbi.nlm.nih.gov/pubmed/30996900
http://dx.doi.org/10.1039/c8sc05103h