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Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

A hydrogenated frustrated Lewis pair ([TMPH(+)][HB(C(6)F(5))(3)(–)]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block seque...

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Detalles Bibliográficos
Autores principales: Sáez, Rubén, McArdle, Ciaran, Salhi, Fouad, Marquet, Jordi, Sebastián, Rosa M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429779/
https://www.ncbi.nlm.nih.gov/pubmed/30996915
http://dx.doi.org/10.1039/c8sc04729d