Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

A hydrogenated frustrated Lewis pair ([TMPH(+)][HB(C(6)F(5))(3)(–)]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block seque...

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Detalles Bibliográficos
Autores principales: Sáez, Rubén, McArdle, Ciaran, Salhi, Fouad, Marquet, Jordi, Sebastián, Rosa M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429779/
https://www.ncbi.nlm.nih.gov/pubmed/30996915
http://dx.doi.org/10.1039/c8sc04729d
Descripción
Sumario:A hydrogenated frustrated Lewis pair ([TMPH(+)][HB(C(6)F(5))(3)(–)]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.

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