Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators

A hydrogenated frustrated Lewis pair ([TMPH(+)][HB(C(6)F(5))(3)(–)]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block seque...

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Detalles Bibliográficos
Autores principales: Sáez, Rubén, McArdle, Ciaran, Salhi, Fouad, Marquet, Jordi, Sebastián, Rosa M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429779/
https://www.ncbi.nlm.nih.gov/pubmed/30996915
http://dx.doi.org/10.1039/c8sc04729d
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author Sáez, Rubén
McArdle, Ciaran
Salhi, Fouad
Marquet, Jordi
Sebastián, Rosa M.
author_facet Sáez, Rubén
McArdle, Ciaran
Salhi, Fouad
Marquet, Jordi
Sebastián, Rosa M.
author_sort Sáez, Rubén
collection PubMed
description A hydrogenated frustrated Lewis pair ([TMPH(+)][HB(C(6)F(5))(3)(–)]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials.
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spelling pubmed-64297792019-04-17 Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators Sáez, Rubén McArdle, Ciaran Salhi, Fouad Marquet, Jordi Sebastián, Rosa M. Chem Sci Chemistry A hydrogenated frustrated Lewis pair ([TMPH(+)][HB(C(6)F(5))(3)(–)]) promotes controlled living ionic polymerization of cyanoacrylates. Controlled growth of various homopolymeric CAs through sequential monomer addition has been achieved, in addition to CA block copolymers with controlled block sequences for the first time in the long history of these materials. Royal Society of Chemistry 2019-02-01 /pmc/articles/PMC6429779/ /pubmed/30996915 http://dx.doi.org/10.1039/c8sc04729d Text en This journal is © The Royal Society of Chemistry 2019 http://creativecommons.org/licenses/by-nc/3.0/ This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)
spellingShingle Chemistry
Sáez, Rubén
McArdle, Ciaran
Salhi, Fouad
Marquet, Jordi
Sebastián, Rosa M.
Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
title Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
title_full Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
title_fullStr Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
title_full_unstemmed Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
title_short Controlled living anionic polymerization of cyanoacrylates by frustrated Lewis pair based initiators
title_sort controlled living anionic polymerization of cyanoacrylates by frustrated lewis pair based initiators
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429779/
https://www.ncbi.nlm.nih.gov/pubmed/30996915
http://dx.doi.org/10.1039/c8sc04729d
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