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Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(ii) catalysts

We report a new strategy for the preparation of dirhodium(ii) complexes with the general formula Rh(2)(A)(4) that allows the isolation of a dirhodium tetracarboxylate complex with a free amino group available for postfunctionalization. The postfunctionalization of this complex enables the incorporat...

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Detalles Bibliográficos
Autores principales: Berndt, Jan-Philipp, Radchenko, Yevhenii, Becker, Jonathan, Logemann, Christian, Bhandari, Dhaka R., Hrdina, Radim, Schreiner, Peter R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429793/
https://www.ncbi.nlm.nih.gov/pubmed/30996919
http://dx.doi.org/10.1039/c8sc05733h