Cargando…

Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(ii) catalysts

We report a new strategy for the preparation of dirhodium(ii) complexes with the general formula Rh(2)(A)(4) that allows the isolation of a dirhodium tetracarboxylate complex with a free amino group available for postfunctionalization. The postfunctionalization of this complex enables the incorporat...

Descripción completa

Detalles Bibliográficos
Autores principales:	Berndt, Jan-Philipp, Radchenko, Yevhenii, Becker, Jonathan, Logemann, Christian, Bhandari, Dhaka R., Hrdina, Radim, Schreiner, Peter R.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6429793/ https://www.ncbi.nlm.nih.gov/pubmed/30996919 http://dx.doi.org/10.1039/c8sc05733h

Ejemplares similares

Postfunctionalized Covalent Organic Frameworks for Water Harvesting
por: Fritz, Patrick W., et al.
Publicado: (2022)

Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex
por: Carsch, Kurtis M., et al.
Publicado: (2023)

Postfunctionalization of Alkyne-Linked Conjugated Carbazole Polymer by Thermal Addition Reaction of Tetracyanoethylene
por: Michinobu, Tsuyoshi, et al.
Publicado: (2010)

Fluoride-Promoted Esterification (FPE) Chemistry: A Robust Route to Bis-MPA Dendrons and Their Postfunctionalization
por: Stenström, Patrik, et al.
Publicado: (2016)

Bis‐Cyclometalated Indazole Chiral‐at‐Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations
por: Steinlandt, Philipp S., et al.
Publicado: (2019)

A New Process for Efficient Recovery of Rhodium from Spent Carbonyl Rhodium Catalyst by Microreactor
por: Guo, Lei, et al.
Publicado: (2023)

Cofactor Controlled Encapsulation of a Rhodium Hydroformylation Catalyst
por: Jongkind, Lukas J., et al.
Publicado: (2019)

An Adaptive Rhodium Catalyst to Control the Hydrogenation Network of Nitroarenes
por: Chugh, Vishal, et al.
Publicado: (2022)

Organocatalytic nitrenoid transfer: metal-free selective intermolecular C(sp(3))–H amination catalyzed by an iminium salt
por: Combee, Logan A., et al.
Publicado: (2017)

Organolithium-Mediated Postfunctionalization of Thiazolo[3,2-c][1,3,5,2]oxadiazaborinine Fluorescent Dyes
por: Potopnyk, Mykhaylo A., et al.
Publicado: (2020)

4,4′-Dicyano- versus 4,4′-Difluoro-BODIPYs in Chemoselective Postfunctionalization Reactions: Synthetic Advantages and Applications
por: Ventura, Juan, et al.
Publicado: (2023)

Catalytic, asymmetric carbon–nitrogen bond formation using metal nitrenoids: from metal–ligand complexes via metalloporphyrins to enzymes
por: Fanourakis, Alexander, et al.
Publicado: (2023)

Effects of ligands on the migratory insertion of alkenes into rhodium–oxygen bonds
por: Richers, Casseday P., et al.
Publicado: (2020)

Non‐Covalent Postfunctionalization of Dye Layers on TiO(2) — A Tool for Enhancing Injection in Dye‐Sensitized Solar Cells
por: Luchs, Tobias, et al.
Publicado: (2021)

A Recyclable Nanoparticle-Supported Rhodium Catalyst for Hydrogenation Reactions
por: Dell’Anna, Maria Michela, et al.
Publicado: (2010)

Size‐Selective Hydroformylation by a Rhodium Catalyst Confined in a Supramolecular Cage
por: Nurttila, Sandra S., et al.
Publicado: (2018)

Synthesis of 1,2-Disubstituted Adamantane Derivatives by Construction of the Adamantane Framework †
por: Todd, Matthew, et al.
Publicado: (2023)

Well-Defined and Robust Rhodium Catalysts for the Hydroacylation of Terminal and Internal Alkenes**
por: Prades, Amparo, et al.
Publicado: (2015)

Rational Optimization of Supramolecular Catalysts for the Rhodium‐Catalyzed Asymmetric Hydrogenation Reaction
por: Daubignard, Julien, et al.
Publicado: (2017)

Ionic Liquids as Solvents for Rhodium and Platinum Catalysts Used in Hydrosilylation Reaction
por: Zielinski, Witold, et al.
Publicado: (2016)

New anionic rhodium complexes as catalysts for the reduction of acetophenone and its derivatives
por: Bartlewicz, Olga, et al.
Publicado: (2019)

Rhodium Catalyst Structural Changes during, and Their Impacts on the Kinetics of, CO Oxidation
por: Marino, Silvia, et al.
Publicado: (2023)

Time-Resolved, In Situ DRIFTS/EDE/MS Studies on Alumina-Supported Rhodium Catalysts: Effects of Ceriation and Zirconiation on Rhodium–CO Interactions**
por: Kroner, Anna B, et al.
Publicado: (2014)

Nanoscale intimacy in bifunctional catalysts for selective conversion of hydrocarbons
por: Zečević, Jovana, et al.
Publicado: (2015)

A bifunctional cerium phosphate catalyst for chemoselective acetalization
por: Kanai, Shunsuke, et al.
Publicado: (2017)

Fluoro Nitrenoid Complexes FN=MF(2) (M=Co, Rh, Ir): Electronic Structure Dichotomy and Formation of Nitrido Fluorides N≡MF(3)
por: Stüker, Tony, et al.
Publicado: (2020)

Combination of supported bimetallic rhodium–molybdenum catalyst and cerium oxide for hydrogenation of amide
por: Nakagawa, Yoshinao, et al.
Publicado: (2015)

Chemoselective dehydrogenative esterification of aldehydes and alcohols with a dimeric rhodium(ii) catalyst
por: Cheng, Junjie, et al.
Publicado: (2016)

In situ spectroscopy-guided engineering of rhodium single-atom catalysts for CO oxidation
por: Hülsey, Max J., et al.
Publicado: (2019)

Asymmetric Hydroformylation Using a Rhodium Catalyst Encapsulated in a Chiral Capsule
por: Jongkind, Lukas J., et al.
Publicado: (2020)

Catalyst Deactivation During Rhodium Complex‐Catalyzed Propargylic C−H Activation
por: Möller, Saskia, et al.
Publicado: (2021)

Rhodium-Based Catalysts: An Impact of the Support Nature on the Catalytic Cyclohexane Ring Opening
por: Kartavova, Kristina E., et al.
Publicado: (2023)

Stability and Activity of Rhodium Promoted Nickel-Based Catalysts in Dry Reforming of Methane
por: Saleh, Jehad, et al.
Publicado: (2023)

Functionalization of Metal Surface via Thiol–Ene Click Chemistry: Synthesis, Adsorption Behavior, and Postfunctionalization of a Catechol- and Allyl-Containing Copolymer
por: Zhang, Yucheng, et al.
Publicado: (2020)

Rhodium Single‐Atom Catalyst Design through Oxide Support Modulation for Selective Gas‐Phase Ethylene Hydroformylation
por: Farpón, Marcos G., et al.
Publicado: (2022)

Tracking the shape-dependent sintering of platinum–rhodium model catalysts under operando conditions
por: Hejral, Uta, et al.
Publicado: (2016)

Correction: Chemoselective dehydrogenative esterification of aldehydes and alcohols with a dimeric rhodium(ii) catalyst
por: Cheng, Junjie, et al.
Publicado: (2017)

A versatile method for the preparation of carbon–rhodium hybrid catalysts on graphene and carbon black
por: Wong, Chin Min, et al.
Publicado: (2016)

Rhodium Porphyrin Bound to a Merrifield Resin as Heterogeneous Catalyst for the Cyclopropanation Reaction of Olefins
por: Ciammaichella, Alina, et al.
Publicado: (2016)

The Choice of Rhodium Catalysts in [2+2+2] Cycloaddition Reaction: A Personal Account
por: Pla-Quintana, Anna, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_ibgji668fk03mcdmqtl8c05qap