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The stability enhancement factor beyond eight-electron shell closure in thiacalix[4]arene-protected silver clusters
We report the synthesis and structures of two 34-atom metal nanoclusters, namely [Ag(34)(BTCA)(3)(C[triple bond, length as m-dash]CBu(t))(9)(tfa)(4)(CH(3)OH)(3)]SbF(6) and [AuAg(33)(BTCA)(3)(C[triple bond, length as m-dash]CBu(t))(9)(tfa)(4)(CH(3)OH)(3)]SbF(6), where H(4)BTCA is p-tert-butylthiacali...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6430012/ https://www.ncbi.nlm.nih.gov/pubmed/30996924 http://dx.doi.org/10.1039/c8sc03756f |