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The stability enhancement factor beyond eight-electron shell closure in thiacalix[4]arene-protected silver clusters

We report the synthesis and structures of two 34-atom metal nanoclusters, namely [Ag(34)(BTCA)(3)(C[triple bond, length as m-dash]CBu(t))(9)(tfa)(4)(CH(3)OH)(3)]SbF(6) and [AuAg(33)(BTCA)(3)(C[triple bond, length as m-dash]CBu(t))(9)(tfa)(4)(CH(3)OH)(3)]SbF(6), where H(4)BTCA is p-tert-butylthiacali...

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Detalles Bibliográficos
Autores principales: Guan, Zong-Jie, Hu, Feng, Yuan, Shang-Fu, Nan, Zi-Ang, Lin, Yu-Mei, Wang, Quan-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6430012/
https://www.ncbi.nlm.nih.gov/pubmed/30996924
http://dx.doi.org/10.1039/c8sc03756f