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Parahydrogen-induced polarization with a metal-free P–P biradicaloid
Metal-free H(2) activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)](2), provides pronounced (1)H and (31)P hyperpolarization wh...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6430094/ https://www.ncbi.nlm.nih.gov/pubmed/30694276 http://dx.doi.org/10.1039/c8cp07625a |