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Parahydrogen-induced polarization with a metal-free P–P biradicaloid

Metal-free H(2) activations are unusual but interesting for catalytic transformations, particularly in parahydrogen-based nuclear spin hyperpolarization techniques. We demonstrate that metal-free singlet phosphorus biradicaloid, [P(μ-NTer)](2), provides pronounced (1)H and (31)P hyperpolarization wh...

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Detalles Bibliográficos
Autores principales:	Zhivonitko, Vladimir V., Bresien, Jonas, Schulz, Axel, Koptyug, Igor V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6430094/ https://www.ncbi.nlm.nih.gov/pubmed/30694276 http://dx.doi.org/10.1039/c8cp07625a

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