Influence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome c oxidase inspired low-spin heme–peroxo–copper complexes

Dioxygen reduction by heme–copper oxidases is a critical biochemical process, wherein hydrogen bonding is hypothesized to participate in the critical step involving the active-site reductive cleavage of the O–O bond. Sixteen novel synthetic heme–(μ-O(2)(2–))–Cu((X)TMPA) complexes, whose design is in...

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Detalles Bibliográficos
Autores principales: Ehudin, Melanie A., Schaefer, Andrew W., Adam, Suzanne M., Quist, David A., Diaz, Daniel E., Tang, Joel A., Solomon, Edward I., Karlin, Kenneth D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431958/
https://www.ncbi.nlm.nih.gov/pubmed/30996867
http://dx.doi.org/10.1039/c8sc05165h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6431958/
https://www.ncbi.nlm.nih.gov/pubmed/30996867
http://dx.doi.org/10.1039/c8sc05165h

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