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Synthesis of Aluminum Complexes Bearing 8-Anilide-5,6,7-trihydroquinoline Ligands: Highly Active Catalyst Precursors for Ring-Opening Polymerization of Cyclic Esters

The stoichiometric reactions of 8-(2,6-R(1)-4-R(2)-anilide)-5,6,7-trihydroquinoline (LH) with AlR(3) (R = Me or Et) afforded the aluminum complexes LAlR(2) (Al1–Al5,Al1: R(1) = (i)Pr, R(2) = H, R = Me; Al2: R(1) = Me, R(2) = H, R = Me; Al3: R(1) = H, R(2) = H, R = Me; Al4: R(1) = Me, R(2) = Me, R =...

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Detalles Bibliográficos
Autores principales: Liu, Shaofeng, Zhang, Jie, Zuo, Weiwei, Zhang, Wenjuan, Sun, Wen-Hua, Ye, Hongqi, Li, Zhibo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432074/
https://www.ncbi.nlm.nih.gov/pubmed/30970764
http://dx.doi.org/10.3390/polym9030083