Copolymerization of Norbornene and Norbornadiene Using a cis-Selective Bimetallic W-Based Catalytic System

The bimetallic cluster Na[W(2)(μ-Cl)(3)Cl(4)(THF)(2)]·(THF)(3) ({W(2)}, {W( 3 )W}(6+), a′(2)e′(4)), which features a triple metal-metal bond, is a highly efficient room-temperature initiator for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and norbornadiene (NBD), providing high...

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Detalles Bibliográficos
Autores principales: Raptopoulos, Grigorios, Kyriakou, Katerina, Mali, Gregor, Scarpellini, Alice, Anyfantis, George C., Mavromoustakos, Thomas, Pitsikalis, Marinos, Paraskevopoulou, Patrina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432165/
https://www.ncbi.nlm.nih.gov/pubmed/30970821
http://dx.doi.org/10.3390/polym9040141

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432165/
https://www.ncbi.nlm.nih.gov/pubmed/30970821
http://dx.doi.org/10.3390/polym9040141

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