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Copolymerization of Norbornene and Norbornadiene Using a cis-Selective Bimetallic W-Based Catalytic System
The bimetallic cluster Na[W(2)(μ-Cl)(3)Cl(4)(THF)(2)]·(THF)(3) ({W(2)}, {W( 3 )W}(6+), a′(2)e′(4)), which features a triple metal-metal bond, is a highly efficient room-temperature initiator for ring opening metathesis polymerization (ROMP) of norbornene (NBE) and norbornadiene (NBD), providing high...
Autores principales: | Raptopoulos, Grigorios, Kyriakou, Katerina, Mali, Gregor, Scarpellini, Alice, Anyfantis, George C., Mavromoustakos, Thomas, Pitsikalis, Marinos, Paraskevopoulou, Patrina |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432165/ https://www.ncbi.nlm.nih.gov/pubmed/30970821 http://dx.doi.org/10.3390/polym9040141 |
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