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Study on the Mechanism of a Side Coupling Reaction during the Living Anionic Copolymerization of Styrene and 1-(Ethoxydimethylsilyphenyl)-1-phenylethylene (DPE-SiOEt)

A 1,1-diphenylethylene (DPE) derivative with an alkoxysilyl group (DPE-SiOEt) was synthesized. It was end-capped with poly(styryl)lithium (PSLi) and then copolymerized with styrene via living anionic polymerization (LAP) in a non-polar solvent at room temperature. The observed side coupling reaction...

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Detalles Bibliográficos
Autores principales: Liu, Pibo, Ma, Hongwei, Shen, Heyu, Han, Li, Chang, Shuang, Zang, Long, Bian, Yiyu, Bai, Yu, Li, Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432263/
https://www.ncbi.nlm.nih.gov/pubmed/30970850
http://dx.doi.org/10.3390/polym9050171