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Highly Active and Isospecific Styrene Polymerization Catalyzed by Zirconium Complexes Bearing Aryl-substituted [OSSO]-Type Bis(phenolate) Ligands

[OSSO]-type dibenzyl zirconium(IV) complexes 9 and 10 possessing aryl substituents ortho to the phenoxide moieties (ortho substituents, phenyl and 2,6-dimethylphenyl (Dmp)) were synthesized and characterized. Upon activation with dMAO (dried methylaluminoxane), complex 9 was found to promote highly...

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Detalles Bibliográficos
Autores principales: Nakata, Norio, Toda, Tomoyuki, Saito, Yusuke, Watanabe, Takanori, Ishii, Akihiko
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432521/
https://www.ncbi.nlm.nih.gov/pubmed/30979125
http://dx.doi.org/10.3390/polym8020031