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Copper-catalyzed 1,4-alkylarylation of 1,3-enynes with masked alkyl electrophiles

Classical 1,4-dicarbofunctionalization of 1,3-enynes employs organometallic reagents as nucleophiles to initiate the reaction. We report a copper-catalyzed 1,4-alkylarylation of 1,3-enynes with alkyl diacyl peroxides as masked alkyl electrophiles and aryl boronic acids as nucleophiles, selectively a...

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Detalles Bibliográficos
Autores principales: Ye, Changqing, Li, Yajun, Zhu, Xiaotao, Hu, Shengmin, Yuan, Daqiang, Bao, Hongli
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6432612/
https://www.ncbi.nlm.nih.gov/pubmed/30996957
http://dx.doi.org/10.1039/c8sc05689g