Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors

The divalent carbene carbon centre in cyclic (alkyl)(amino)carbenes (CAACs) is known to exhibit transition-metal-like insertion into E–H σ-bonds (E = H, N, Si, B, P, C, O) with formation of new, strong C–E and C–H bonds. Although subsequent transformations of the products represent an attractive str...

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Detalles Bibliográficos
Autores principales: Oldroyd, Nicola L., Chitnis, Saurabh S., Annibale, Vincent T., Arz, Marius I., Sparkes, Hazel A., Manners, Ian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6435733/
https://www.ncbi.nlm.nih.gov/pubmed/30914640
http://dx.doi.org/10.1038/s41467-019-08967-8

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6435733/
https://www.ncbi.nlm.nih.gov/pubmed/30914640
http://dx.doi.org/10.1038/s41467-019-08967-8

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