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Metal-free dehydropolymerisation of phosphine-boranes using cyclic (alkyl)(amino)carbenes as hydrogen acceptors
The divalent carbene carbon centre in cyclic (alkyl)(amino)carbenes (CAACs) is known to exhibit transition-metal-like insertion into E–H σ-bonds (E = H, N, Si, B, P, C, O) with formation of new, strong C–E and C–H bonds. Although subsequent transformations of the products represent an attractive str...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6435733/ https://www.ncbi.nlm.nih.gov/pubmed/30914640 http://dx.doi.org/10.1038/s41467-019-08967-8 |