Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
Control of self-assembly is significant to the preparation of supramolecular materials and illustration of diversities in either natural or artificial systems. Supra-amphiphiles have remarkable advantages in the construction of nanostructures but control of shape and size of supramolecular nanostruc...
Autores principales: | , , , , , , , , , , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2019
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6438973/ https://www.ncbi.nlm.nih.gov/pubmed/30923311 http://dx.doi.org/10.1038/s41467-019-09363-y |
_version_ | 1783407184452780032 |
---|---|
author | Wang, Shu-Ping Lin, Wei Wang, Xiaolin Cen, Tian-Yong Xie, Hujun Huang, Jianying Zhu, Ben-Yue Zhang, Zibin Song, Aixin Hao, Jingcheng Wu, Jing Li, Shijun |
author_facet | Wang, Shu-Ping Lin, Wei Wang, Xiaolin Cen, Tian-Yong Xie, Hujun Huang, Jianying Zhu, Ben-Yue Zhang, Zibin Song, Aixin Hao, Jingcheng Wu, Jing Li, Shijun |
author_sort | Wang, Shu-Ping |
collection | PubMed |
description | Control of self-assembly is significant to the preparation of supramolecular materials and illustration of diversities in either natural or artificial systems. Supra-amphiphiles have remarkable advantages in the construction of nanostructures but control of shape and size of supramolecular nanostructures is still a great challenge. Here, we fabricate a series of supra-amphiphiles by utilizing the recognition motifs based on a heteroditopic porphyrin amphiphile and its zinc complex. These porphyrin amphiphiles can bind with a few guests including Cl(–), coronene, C(60), 4,4′-bipyridine and 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, which are further applied to facilitate the controllable self-assembly. Addition of these guests result in the formation of various supra-amphiphiles with well-defined structures, thus induce the generation of different aggregates. A diverse of aggregation morphologies including nanospheres, nanorods, films, spheric micelles, vesicles and macrowires are constructed upon the influence of specific complexation, which highlights the present work with abundant control on the shapes and dimensions of self-assemblies. |
format | Online Article Text |
id | pubmed-6438973 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2019 |
publisher | Nature Publishing Group UK |
record_format | MEDLINE/PubMed |
spelling | pubmed-64389732019-04-01 Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles Wang, Shu-Ping Lin, Wei Wang, Xiaolin Cen, Tian-Yong Xie, Hujun Huang, Jianying Zhu, Ben-Yue Zhang, Zibin Song, Aixin Hao, Jingcheng Wu, Jing Li, Shijun Nat Commun Article Control of self-assembly is significant to the preparation of supramolecular materials and illustration of diversities in either natural or artificial systems. Supra-amphiphiles have remarkable advantages in the construction of nanostructures but control of shape and size of supramolecular nanostructures is still a great challenge. Here, we fabricate a series of supra-amphiphiles by utilizing the recognition motifs based on a heteroditopic porphyrin amphiphile and its zinc complex. These porphyrin amphiphiles can bind with a few guests including Cl(–), coronene, C(60), 4,4′-bipyridine and 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, which are further applied to facilitate the controllable self-assembly. Addition of these guests result in the formation of various supra-amphiphiles with well-defined structures, thus induce the generation of different aggregates. A diverse of aggregation morphologies including nanospheres, nanorods, films, spheric micelles, vesicles and macrowires are constructed upon the influence of specific complexation, which highlights the present work with abundant control on the shapes and dimensions of self-assemblies. Nature Publishing Group UK 2019-03-28 /pmc/articles/PMC6438973/ /pubmed/30923311 http://dx.doi.org/10.1038/s41467-019-09363-y Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. |
spellingShingle | Article Wang, Shu-Ping Lin, Wei Wang, Xiaolin Cen, Tian-Yong Xie, Hujun Huang, Jianying Zhu, Ben-Yue Zhang, Zibin Song, Aixin Hao, Jingcheng Wu, Jing Li, Shijun Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles |
title | Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles |
title_full | Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles |
title_fullStr | Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles |
title_full_unstemmed | Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles |
title_short | Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles |
title_sort | controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6438973/ https://www.ncbi.nlm.nih.gov/pubmed/30923311 http://dx.doi.org/10.1038/s41467-019-09363-y |
work_keys_str_mv | AT wangshuping controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT linwei controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT wangxiaolin controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT centianyong controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT xiehujun controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT huangjianying controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT zhubenyue controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT zhangzibin controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT songaixin controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT haojingcheng controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT wujing controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles AT lishijun controllablehierarchicalselfassemblyofporphyrinderivedsupraamphiphiles |