Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles

Control of self-assembly is significant to the preparation of supramolecular materials and illustration of diversities in either natural or artificial systems. Supra-amphiphiles have remarkable advantages in the construction of nanostructures but control of shape and size of supramolecular nanostruc...

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Autores principales: Wang, Shu-Ping, Lin, Wei, Wang, Xiaolin, Cen, Tian-Yong, Xie, Hujun, Huang, Jianying, Zhu, Ben-Yue, Zhang, Zibin, Song, Aixin, Hao, Jingcheng, Wu, Jing, Li, Shijun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6438973/
https://www.ncbi.nlm.nih.gov/pubmed/30923311
http://dx.doi.org/10.1038/s41467-019-09363-y
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author Wang, Shu-Ping
Lin, Wei
Wang, Xiaolin
Cen, Tian-Yong
Xie, Hujun
Huang, Jianying
Zhu, Ben-Yue
Zhang, Zibin
Song, Aixin
Hao, Jingcheng
Wu, Jing
Li, Shijun
author_facet Wang, Shu-Ping
Lin, Wei
Wang, Xiaolin
Cen, Tian-Yong
Xie, Hujun
Huang, Jianying
Zhu, Ben-Yue
Zhang, Zibin
Song, Aixin
Hao, Jingcheng
Wu, Jing
Li, Shijun
author_sort Wang, Shu-Ping
collection PubMed
description Control of self-assembly is significant to the preparation of supramolecular materials and illustration of diversities in either natural or artificial systems. Supra-amphiphiles have remarkable advantages in the construction of nanostructures but control of shape and size of supramolecular nanostructures is still a great challenge. Here, we fabricate a series of supra-amphiphiles by utilizing the recognition motifs based on a heteroditopic porphyrin amphiphile and its zinc complex. These porphyrin amphiphiles can bind with a few guests including Cl(–), coronene, C(60), 4,4′-bipyridine and 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, which are further applied to facilitate the controllable self-assembly. Addition of these guests result in the formation of various supra-amphiphiles with well-defined structures, thus induce the generation of different aggregates. A diverse of aggregation morphologies including nanospheres, nanorods, films, spheric micelles, vesicles and macrowires are constructed upon the influence of specific complexation, which highlights the present work with abundant control on the shapes and dimensions of self-assemblies.
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spelling pubmed-64389732019-04-01 Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles Wang, Shu-Ping Lin, Wei Wang, Xiaolin Cen, Tian-Yong Xie, Hujun Huang, Jianying Zhu, Ben-Yue Zhang, Zibin Song, Aixin Hao, Jingcheng Wu, Jing Li, Shijun Nat Commun Article Control of self-assembly is significant to the preparation of supramolecular materials and illustration of diversities in either natural or artificial systems. Supra-amphiphiles have remarkable advantages in the construction of nanostructures but control of shape and size of supramolecular nanostructures is still a great challenge. Here, we fabricate a series of supra-amphiphiles by utilizing the recognition motifs based on a heteroditopic porphyrin amphiphile and its zinc complex. These porphyrin amphiphiles can bind with a few guests including Cl(–), coronene, C(60), 4,4′-bipyridine and 2,4,6-tri(pyridin-4-yl)-1,3,5-triazine, which are further applied to facilitate the controllable self-assembly. Addition of these guests result in the formation of various supra-amphiphiles with well-defined structures, thus induce the generation of different aggregates. A diverse of aggregation morphologies including nanospheres, nanorods, films, spheric micelles, vesicles and macrowires are constructed upon the influence of specific complexation, which highlights the present work with abundant control on the shapes and dimensions of self-assemblies. Nature Publishing Group UK 2019-03-28 /pmc/articles/PMC6438973/ /pubmed/30923311 http://dx.doi.org/10.1038/s41467-019-09363-y Text en © The Author(s) 2019 Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
spellingShingle Article
Wang, Shu-Ping
Lin, Wei
Wang, Xiaolin
Cen, Tian-Yong
Xie, Hujun
Huang, Jianying
Zhu, Ben-Yue
Zhang, Zibin
Song, Aixin
Hao, Jingcheng
Wu, Jing
Li, Shijun
Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
title Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
title_full Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
title_fullStr Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
title_full_unstemmed Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
title_short Controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
title_sort controllable hierarchical self-assembly of porphyrin-derived supra-amphiphiles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6438973/
https://www.ncbi.nlm.nih.gov/pubmed/30923311
http://dx.doi.org/10.1038/s41467-019-09363-y
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