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Synthesis of functionalized diazocines for application as building blocks in photo- and mechanoresponsive materials

Seven symmetrically 3,3’-substituted diazocines were synthesized. Functional groups include alcohol, azide, amine and vinyl groups, which are suitable for polymer synthesis. Upon irradiation at 385 and 530 nm the diazocines perform a reversible, pincer-type movement switching the 3,3’-distance betwe...

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Detalles Bibliográficos
Autores principales: Moormann, Widukind, Langbehn, Daniel, Herges, Rainer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6444418/
https://www.ncbi.nlm.nih.gov/pubmed/30992720
http://dx.doi.org/10.3762/bjoc.15.68