Thorium- and uranium-azide reductions: a transient dithorium-nitride versus isolable diuranium-nitrides

Molecular uranium-nitrides are now well known, but there are no isolable molecular thorium-nitrides outside of cryogenic matrix isolation experiments. We report that treatment of [M(Tren(DMBS))(I)] (M = U, 1; Th, 2; Tren(DMBS) = {N(CH(2)CH(2)NSiMe(2)Bu(t))(3)}(3–)) with NaN(3) or KN(3), respectively...

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Detalles Bibliográficos
Autores principales: Du, Jingzhen, King, David M., Chatelain, Lucile, Lu, Erli, Tuna, Floriana, McInnes, Eric J. L., Wooles, Ashley J., Maron, Laurent, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6446963/
https://www.ncbi.nlm.nih.gov/pubmed/30996964
http://dx.doi.org/10.1039/c8sc05473h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6446963/
https://www.ncbi.nlm.nih.gov/pubmed/30996964
http://dx.doi.org/10.1039/c8sc05473h

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