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Structural Properties of Gas Phase Molybdenum Sulfide Clusters [Mo(3)S(13)](2–), [HMo(3)S(13)](−), and [H(3)Mo(3)S(13)](+) as Model Systems of a Promising Hydrogen Evolution Catalyst

[Image: see text] Amorphous molybdenum sulfide (MoS(x)) is a potent catalyst for the hydrogen evolution reaction (HER). Since mechanistic investigations on amorphous solids are particularly difficult, we use a bottom-up approach and study the [Mo(3)S(13)](2–) nanocluster and its protonated forms. Th...

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Detalles Bibliográficos
Autores principales: Baloglou, Aristeidis, Ončák, Milan, Grutza, Marie-Luise, van der Linde, Christian, Kurz, Philipp, Beyer, Martin K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6453024/
https://www.ncbi.nlm.nih.gov/pubmed/30984322
http://dx.doi.org/10.1021/acs.jpcc.8b08324