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Structural Properties of Gas Phase Molybdenum Sulfide Clusters [Mo(3)S(13)](2–), [HMo(3)S(13)](−), and [H(3)Mo(3)S(13)](+) as Model Systems of a Promising Hydrogen Evolution Catalyst
[Image: see text] Amorphous molybdenum sulfide (MoS(x)) is a potent catalyst for the hydrogen evolution reaction (HER). Since mechanistic investigations on amorphous solids are particularly difficult, we use a bottom-up approach and study the [Mo(3)S(13)](2–) nanocluster and its protonated forms. Th...
Autores principales: | Baloglou, Aristeidis, Ončák, Milan, Grutza, Marie-Luise, van der Linde, Christian, Kurz, Philipp, Beyer, Martin K. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical
Society
2018
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6453024/ https://www.ncbi.nlm.nih.gov/pubmed/30984322 http://dx.doi.org/10.1021/acs.jpcc.8b08324 |
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