Dehydropolymerization of H(3)B·NMeH(2) Using a [Rh(DPEphos)](+) Catalyst: The Promoting Effect of NMeH(2)

[Image: see text] [Rh(κ(2)-PP-DPEphos){η(2)η(2)-H(2)B(NMe(3))(CH(2))(2)(t)Bu}][BAr(F)(4)] acts as an effective precatalyst for the dehydropolymerization of H(3)B·NMeH(2) to form N-methylpolyaminoborane (H(2)BNMeH)(n). Control of polymer molecular weight is achieved by variation of precatalyst loadin...

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Detalles Bibliográficos
Autores principales: Adams, Gemma M., Ryan, David E., Beattie, Nicholas A., McKay, Alasdair I., Lloyd-Jones, Guy C., Weller, Andrew S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6454579/
https://www.ncbi.nlm.nih.gov/pubmed/30984472
http://dx.doi.org/10.1021/acscatal.9b00081

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6454579/
https://www.ncbi.nlm.nih.gov/pubmed/30984472
http://dx.doi.org/10.1021/acscatal.9b00081

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