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Dehydropolymerization of H(3)B·NMeH(2) Using a [Rh(DPEphos)](+) Catalyst: The Promoting Effect of NMeH(2)
[Image: see text] [Rh(κ(2)-PP-DPEphos){η(2)η(2)-H(2)B(NMe(3))(CH(2))(2)(t)Bu}][BAr(F)(4)] acts as an effective precatalyst for the dehydropolymerization of H(3)B·NMeH(2) to form N-methylpolyaminoborane (H(2)BNMeH)(n). Control of polymer molecular weight is achieved by variation of precatalyst loadin...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6454579/ https://www.ncbi.nlm.nih.gov/pubmed/30984472 http://dx.doi.org/10.1021/acscatal.9b00081 |