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Dithiane-directed Rh(iii)-catalyzed amidation of unactivated C(sp(3))–H bonds
An oxidant-free Rh(iii)-catalyzed direct amidation of alkyl dithianes via C(sp(3))–H bond activation utilizing diverse and robust dioxazolone reagents is reported. The reaction hinges on use of a Cp*Rh(iii) complex in combination with an essential amino-carboxylate additive to generate usefully prot...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6457195/ https://www.ncbi.nlm.nih.gov/pubmed/31015917 http://dx.doi.org/10.1039/c8sc05225e |