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Dithiane-directed Rh(iii)-catalyzed amidation of unactivated C(sp(3))–H bonds

An oxidant-free Rh(iii)-catalyzed direct amidation of alkyl dithianes via C(sp(3))–H bond activation utilizing diverse and robust dioxazolone reagents is reported. The reaction hinges on use of a Cp*Rh(iii) complex in combination with an essential amino-carboxylate additive to generate usefully prot...

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Detalles Bibliográficos
Autores principales: Shi, Heyao, Dixon, Darren J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6457195/
https://www.ncbi.nlm.nih.gov/pubmed/31015917
http://dx.doi.org/10.1039/c8sc05225e

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