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Controlling a burn: outer-sphere gating of hydroxylamine oxidation by a distal base in cytochrome P460
Ammonia oxidizing bacteria (AOB) use the cytotoxic, energetic molecule hydroxylamine (NH(2)OH) as a source of reducing equivalents for cellular respiration. Despite disproportionation or violent decomposition being typical outcomes of reactions of NH(2)OH with iron, AOB and anammox heme P460 protein...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6457333/ https://www.ncbi.nlm.nih.gov/pubmed/31015919 http://dx.doi.org/10.1039/c9sc00195f |