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Controlling a burn: outer-sphere gating of hydroxylamine oxidation by a distal base in cytochrome P460

Ammonia oxidizing bacteria (AOB) use the cytotoxic, energetic molecule hydroxylamine (NH(2)OH) as a source of reducing equivalents for cellular respiration. Despite disproportionation or violent decomposition being typical outcomes of reactions of NH(2)OH with iron, AOB and anammox heme P460 protein...

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Detalles Bibliográficos
Autores principales:	Smith, Meghan A., Majer, Sean H., Vilbert, Avery C., Lancaster, Kyle M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Royal Society of Chemistry 2019
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6457333/ https://www.ncbi.nlm.nih.gov/pubmed/31015919 http://dx.doi.org/10.1039/c9sc00195f

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