Facile Conversion of syn‐[Fe(IV)(O)(TMC)](2+) into the anti Isomer via Meunier's Oxo–Hydroxo Tautomerism Mechanism

The syn and anti isomers of [Fe(IV)(O)(TMC)](2+) (TMC=tetramethylcyclam) represent the first isolated pair of synthetic non‐heme oxoiron(IV) complexes with identical ligand topology, differing only in the position of the oxo unit bound to the iron center. Both isomers have previously been characteri...

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Detalles Bibliográficos
Autores principales: Prakash, Jai, Sheng, Yuan, Draksharapu, Apparao, Klein, Johannes E. M. N., Cramer, Christopher J., Que, Lawrence
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470793/
https://www.ncbi.nlm.nih.gov/pubmed/30556289
http://dx.doi.org/10.1002/anie.201811454

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470793/
https://www.ncbi.nlm.nih.gov/pubmed/30556289
http://dx.doi.org/10.1002/anie.201811454

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