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Facile Conversion of syn‐[Fe(IV)(O)(TMC)](2+) into the anti Isomer via Meunier's Oxo–Hydroxo Tautomerism Mechanism
The syn and anti isomers of [Fe(IV)(O)(TMC)](2+) (TMC=tetramethylcyclam) represent the first isolated pair of synthetic non‐heme oxoiron(IV) complexes with identical ligand topology, differing only in the position of the oxo unit bound to the iron center. Both isomers have previously been characteri...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470793/ https://www.ncbi.nlm.nih.gov/pubmed/30556289 http://dx.doi.org/10.1002/anie.201811454 |