T(1) Population as the Driver of Excited‐State Proton‐Transfer in 2‐Thiopyridone

Excited‐state proton transfer (ESPT) is a fundamental process in biomolecular photochemistry, but its underlying mediators often evade direct observation. We identify a distinct pathway for ESPT in aqueous 2‐thiopyridone, by employing transient N 1s X‐ray absorption spectroscopy and multi‐configurat...

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Detalles Bibliográficos
Autores principales: Eckert, Sebastian, Norell, Jesper, Jay, Raphael M., Fondell, Mattis, Mitzner, Rolf, Odelius, Michael, Föhlisch, Alexander
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470867/
https://www.ncbi.nlm.nih.gov/pubmed/30452789
http://dx.doi.org/10.1002/chem.201804166

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6470867/
https://www.ncbi.nlm.nih.gov/pubmed/30452789
http://dx.doi.org/10.1002/chem.201804166

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